Structure of the Atom: notes and practice questions
- This topic explores the relationship between nuclear radius and nucleon number, discrete energy levels in the Bohr model, and quantized angular momentum.
- The nuclear radius is related to the nucleon number by , where is a constant.
- The discrete energy levels in the Bohr model for hydrogen are given by eV.
- The angular momentum of an electron in the Bohr model is quantized as .
- Deviations from Rutherford scattering at high energies and the calculation of the distance of closest approach are also covered.
How it is examined
Both papers, with the scattering and Bohr content HL only. May 2025 HL Paper 2 TZ1 question 3(a) asked, in two parts, explain why alpha scattering deviates from the Rutherford model at high energy (1 mark: the alpha is within range of the strong nuclear force) and explain how an initial energy estimates the nuclear radius (2 marks: recognize that the nuclear radius is approximately the distance of closest approach, then set initial kinetic energy equal to ). The mark scheme said explicitly that using r in an algebraic expression is not enough for the first marking point, which is a good illustration of how tightly "explains" is read.
SL: , Planck's constant, the electronvolt conversion. HL adds with , the Bohr energy-level formula and . Chemical symbols are explicitly not required, so a question that depends on knowing that Au is gold should name the element in words.
- the Geiger-Marsden-Rutherford experiment and the discovery of the nucleus
- nuclear notation , where A is the nucleon number, Z the proton number and X the chemical symbol
- that emission and absorption spectra provide evidence for discrete atomic energy levels
- that photons are emitted and absorbed during atomic transitions
Recall of chemical symbols is not required.
Guiding questions
- What is the current understanding of the nature of an atom?
- What is the role of evidence in the development of models of the atom?
- In what ways are previous models of the atom still valid despite recent advances in understanding?
Linking questions
- How can emission spectra allow for the properties of stars to be deduced?
- How is the distance of closest approach calculated using conservation of energy?
- How can emission spectra be used to calculate the distances and velocities of celestial bodies?
- Under what circumstances does the Bohr model fail? (NOS)
- How have observations led to developments in the model of the atom? (NOS)
Practice questions
5 questions · 5 mediumQuestion 1
MediumPaper 2 · calculator5 marksThe fine-structure constant, , is a fundamental physical constant that characterizes the strength of the electromagnetic interaction. It is given by the expression .
(a) Show that the quantity has units of energy multiplied by distance.
(b) Hence, show that the fine-structure constant is dimensionless.
Consider the formula for either the electrostatic force or the electric potential energy between two elementary charges.
Determine the units of the denominator, . You can find the units of the reduced Planck constant, , from a relationship like or the de Broglie relation. Remember that .
Question 2
MediumPaper 2 · calculator6 marksIn a hypothetical experiment simulating Rutherford scattering, alpha particles are accelerated towards a thin foil of Uranium. The alpha particles, with a mass of , approach the Uranium nuclei with an initial speed of . The atomic number for Uranium is .
(a) Calculate the closest distance of approach for these alpha particles to a Uranium nucleus.
(b) State two assumptions made in this calculation regarding the interaction between the alpha particle and the nucleus.
At the point of closest approach, all the initial kinetic energy of the alpha particle is converted into electric potential energy. Remember the charges of an alpha particle and a nucleus.
Consider the forces involved and the nature of the particles themselves.
Question 3
MediumPaper 1A · calculator1 markThe energy levels of a hydrogen atom are given by the formula eV, where is the principal quantum number.
Consider two transitions in a hydrogen atom:
Transition P: An electron moves from the energy level to the energy level.
Transition Q: An electron moves from the energy level to the energy level.
What is the ratio ?
A.
B.
C.
D.
Calculate the energy absorbed for each transition using the given formula. Remember that energy absorbed is the absolute difference between the final and initial energy levels. Then form the ratio.
Question 4
MediumPaper 1A · calculator1 markAn alpha particle () with an initial kinetic energy of is directed towards the center of a stationary lead nucleus (). The alpha particle approaches the nucleus head-on.
What is the distance of closest approach of the alpha particle to the lead nucleus?
A.
B.
C.
D.
At the distance of closest approach, the initial kinetic energy of the alpha particle is entirely converted into electrostatic potential energy. Remember to use the correct charges for the alpha particle and the lead nucleus, and convert the energy to joules.
Question 5
MediumPaper 1A · calculator1 markAn electron in a hydrogen-like ion absorbs a photon of energy to make a transition from the to the state. The energy levels of the ion are given by .
What photon energy is required for a transition from the to the state?
A.
B.
C.
D.
First find the value of the constant using the energy difference between the and states. Then use this to find the energy difference between the and states.
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Where marks are lost
- Stopping one step short of the conclusion. Two numbers and no sentence is two marks out of three.
- Answering a procedure question with a platitude.
- Losing precision in Paper 1B. Uniquely to this paper, quoting the right number badly loses marks.