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Topic S1.5 · HL only

Ideal gases: notes and practice questions

Summary
  • This topic covers the ideal gas model, its assumptions, and the behavior of real gases.
  • It includes the ideal gas equation PV=nRTPV = nRT and the combined gas law P1V1T1=P2V2T2\frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2}.
  • The IB Chemistry guide specifies that there is no additional higher level content for this topic beyond what is covered by both Standard Level and Higher Level students.

How it is examined

Paper 1A multiple choice on which conditions cause the largest deviation, and Paper 2 calculations that rearrange PV = nRT. Because the equation is in the booklet, a question testing recall of it is worthless; the assessable part is unit conversion (cm³ to m³, kPa to Pa, °C to K) and the rearrangement. May 2025 HL Paper 2 TZ1 used the molar volume route rather than PV = nRT for a gas volume, which is the more common SL shape.

Given in the booklet

The gas constant R, the ideal gas equation PV = nRT, the combined gas law, and the molar volume of an ideal gas at STP. The assumptions of the ideal gas model and the conditions for deviation are recall.

Key ideas
  • 1.5.1 An ideal gas consists of moving particles with negligible volume and no intermolecular forces. All collisions between particles are considered elastic. Students recognize the key assumptions in the ideal gas model.
  • 1.5.2 Real gases deviate from the ideal gas model, particularly at low temperature and high pressure. Students explain the limitations of the ideal gas model.
  • 1.5.3 The molar volume of an ideal gas is a constant at a specific temperature and pressure. Students investigate the relationship between temperature, pressure and volume for a fixed mass of an ideal gas and analyse graphs relating these variables.
  • 1.5.4 The relationship between pressure, volume, temperature and amount of an ideal gas is shown in the ideal gas equation `PV = nRT` and the combined gas law `P₁V₁ / T₁ = P₂V₂ / T₂`. Students solve problems relating to the ideal gas equation.
Not assessed

The names of specific gas laws will not be assessed. Do not ask for Boyle, Charles or Gay-Lussac by name.

Guiding questions

  • How does the model of ideal gas behaviour help us to predict the behaviour of real gases?

Linking questions

  • Structure 2.2 Under comparable conditions, why do some gases deviate more from ideal behaviour than others?
  • Nature of science, Tools 2 and 3, Reactivity 2.2 Graphs can be presented as sketches or as accurately plotted data points. What are the advantages and limitations of each representation?
  • Tool 1, Inquiry 2 How can the ideal gas law be used to calculate the molar mass of a gas from experimental data?

Practice questions

5 questions · 1 easy · 4 medium
Showing 5 of 5

Question 1

EasyPaper 1A · calculator1 mark

In which of the following sets of conditions does the gas exhibit behaviour closest to an ideal gas?

A. Helium, 200 kPa200\text{ kPa}, 200 K200\text{ K}

B. Sulfur dioxide, 20 kPa20\text{ kPa}, 500 K500\text{ K}

C. Helium, 20 kPa20\text{ kPa}, 500 K500\text{ K}

D. Sulfur dioxide, 200 kPa200\text{ kPa}, 200 K200\text{ K}

Question 2

MediumPaper 1A · calculator1 mark

A sealed container holds a fixed amount of an ideal gas. If the pressure exerted by the gas is reduced to 25%25\% of its initial value, while maintaining a constant temperature, what is the effect on the volume of the gas?

A. The volume increases by 100%100\%.

B. The volume increases by 200%200\%.

C. The volume increases by 300%300\%.

D. The volume decreases by 75%75\%.

Question 3

MediumPaper 1A · calculator1 mark

A sample of butane, C4H10(g)C_4H_{10}(g), with a volume of 2.50 dm32.50 \text{ dm}^3 is collected at 25.0 °C25.0 \text{ °C} and 100.0 kPa100.0 \text{ kPa}. How many moles of oxygen are needed for the complete combustion of this sample of butane?

A. 0.1010.101

B. 0.3280.328

C. 0.6560.656

D. 1.311.31

Question 4

MediumPaper 1A · calculator1 mark

A sealed, rigid container holds a sample of an ideal gas. Initially, the gas is at 20 ∘C20 \text{ } ^\circ C with a pressure of PinitialP_{\text{initial}} kPa. The container is then moved to a warmer environment, causing the gas temperature to rise to 50 ∘C50 \text{ } ^\circ C.

What is the resulting pressure in kPa?

A. Half of PinitialP_{\text{initial}}

B. A little less than PinitialP_{\text{initial}}

C. A little more than PinitialP_{\text{initial}}

D. Two times PinitialP_{\text{initial}}

Question 5

MediumPaper 1A · calculator1 mark

A sealed reaction vessel of fixed volume contains a sample of nitrogen gas at an initial pressure of 60 kPa60\ kPa and a temperature of 290 K290\ K. During a process, 1/51/5 of the nitrogen molecules are removed from the vessel, and the temperature is simultaneously increased to 435 K435\ K.

What is the new pressure of the gas in kPakPa?

A. 18 kPa18\ kPa

B. 48 kPa48\ kPa

C. 72 kPa72\ kPa

D. 90 kPa90\ kPa

Every Ideal gases question, marked for you

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Where marks are lost

  • Reaching for "human error" or "only one trial." A source of error has to be a specific step in the method, not a general apology for the result.
  • Joining the dots instead of drawing a curve.
  • Naming a chemical instead of the property that distinguishes it, or vice versa. Answering with the nearest fact that comes to mind rather than the fact the command term and stem jointly ask for is a recurring way to answer a question that was not, quite, the one asked.
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What does Ideal gases cover in IB Chemistry?

This topic covers the ideal gas model, its assumptions, and the behavior of real gases. It includes the ideal gas equation PV = nRT and the combined gas law (P_1V_1)/(T_1) = (P_2V_2)/(T_2). The IB Chemistry guide specifies that there is no additional higher level content for this topic beyond what is covered by both Standard Level and Higher Level students.

Is Ideal gases SL or HL?

Ideal gases is HL only. SL students are not examined on it.

How do I revise Ideal gases for IB Chemistry?

Start from the core idea: this topic covers the ideal gas model, its assumptions, and the behavior of real gases. In the exam: paper 1A multiple choice on which conditions cause the largest deviation, and Paper 2 calculations that rearrange PV = nRT. Because the equation is in the booklet, a question testing recall of it is worthless; the assessable part is unit conversion (cm³ to m³, kPa to Pa, °C to K) and the rearrangement. Then practise exam-style questions, easiest first, writing out every step of your working before you check it.

How does FourtyFive help me practise Ideal gases?

FourtyFive has 5 Ideal gases questions. Every answer you write is marked mark by mark, IB-style, and you see where each mark was won or lost. Every part has a hint, the AI tutor helps you through the step you are stuck on, and your Study Profile picks what to practise next.

Is FourtyFive free for Ideal gases practice?

Yes. A free account gives you 50 marked answers a month, and you do not need a card to sign up.

Can I handwrite Ideal gases answers on an iPad?

Yes. In the FourtyFive iPad app you write your working by hand with Apple Pencil, the way you would on paper, and it is marked the same way.

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