Ideal gases: notes and practice questions
- This topic covers the ideal gas model, its assumptions, and the behavior of real gases.
- It includes the ideal gas equation and the combined gas law .
- The IB Chemistry guide specifies that there is no additional higher level content for this topic beyond what is covered by both Standard Level and Higher Level students.
How it is examined
Paper 1A multiple choice on which conditions cause the largest deviation, and Paper 2 calculations that rearrange PV = nRT. Because the equation is in the booklet, a question testing recall of it is worthless; the assessable part is unit conversion (cm³ to m³, kPa to Pa, °C to K) and the rearrangement. May 2025 HL Paper 2 TZ1 used the molar volume route rather than PV = nRT for a gas volume, which is the more common SL shape.
The gas constant R, the ideal gas equation PV = nRT, the combined gas law, and the molar volume of an ideal gas at STP. The assumptions of the ideal gas model and the conditions for deviation are recall.
- 1.5.1 An ideal gas consists of moving particles with negligible volume and no intermolecular forces. All collisions between particles are considered elastic. Students recognize the key assumptions in the ideal gas model.
- 1.5.2 Real gases deviate from the ideal gas model, particularly at low temperature and high pressure. Students explain the limitations of the ideal gas model.
- 1.5.3 The molar volume of an ideal gas is a constant at a specific temperature and pressure. Students investigate the relationship between temperature, pressure and volume for a fixed mass of an ideal gas and analyse graphs relating these variables.
- 1.5.4 The relationship between pressure, volume, temperature and amount of an ideal gas is shown in the ideal gas equation `PV = nRT` and the combined gas law `P₁V₁ / T₁ = P₂V₂ / T₂`. Students solve problems relating to the ideal gas equation.
The names of specific gas laws will not be assessed. Do not ask for Boyle, Charles or Gay-Lussac by name.
Guiding questions
- How does the model of ideal gas behaviour help us to predict the behaviour of real gases?
Linking questions
- Structure 2.2 Under comparable conditions, why do some gases deviate more from ideal behaviour than others?
- Nature of science, Tools 2 and 3, Reactivity 2.2 Graphs can be presented as sketches or as accurately plotted data points. What are the advantages and limitations of each representation?
- Tool 1, Inquiry 2 How can the ideal gas law be used to calculate the molar mass of a gas from experimental data?
Practice questions
5 questions · 1 easy · 4 mediumQuestion 1
EasyPaper 1A · calculator1 markIn which of the following sets of conditions does the gas exhibit behaviour closest to an ideal gas?
A. Helium, ,
B. Sulfur dioxide, ,
C. Helium, ,
D. Sulfur dioxide, ,
Ideal gas behaviour is favoured by conditions that minimize the effect of intermolecular forces and the volume of the gas particles. Consider which temperature (high or low) and pressure (high or low) achieves this. Also, compare the intermolecular forces present in helium and sulfur dioxide.
Question 2
MediumPaper 1A · calculator1 markA sealed container holds a fixed amount of an ideal gas. If the pressure exerted by the gas is reduced to of its initial value, while maintaining a constant temperature, what is the effect on the volume of the gas?
A. The volume increases by .
B. The volume increases by .
C. The volume increases by .
D. The volume decreases by .
Recall Boyle's Law, which states that for a fixed amount of gas at constant temperature, pressure and volume are inversely proportional. Consider how a reduction in pressure affects the volume and then calculate the percentage change.
Question 3
MediumPaper 1A · calculator1 markA sample of butane, , with a volume of is collected at and . How many moles of oxygen are needed for the complete combustion of this sample of butane?
A.
B.
C.
D.
First, write a balanced chemical equation for the complete combustion of butane. Then, use the ideal gas law () to find the moles of butane. Finally, use the stoichiometric ratio from the balanced equation to determine the moles of oxygen. Remember to convert units appropriately for the ideal gas law ( in Pa, in m, in K, ).
Question 4
MediumPaper 1A · calculator1 markA sealed, rigid container holds a sample of an ideal gas. Initially, the gas is at with a pressure of kPa. The container is then moved to a warmer environment, causing the gas temperature to rise to .
What is the resulting pressure in kPa?
A. Half of
B. A little less than
C. A little more than
D. Two times
Remember to convert temperatures to the absolute temperature scale (Kelvin) before applying the ideal gas law. For a fixed volume, pressure is directly proportional to absolute temperature.
Question 5
MediumPaper 1A · calculator1 markA sealed reaction vessel of fixed volume contains a sample of nitrogen gas at an initial pressure of and a temperature of . During a process, of the nitrogen molecules are removed from the vessel, and the temperature is simultaneously increased to .
What is the new pressure of the gas in ?
A.
B.
C.
D.
Recall the ideal gas law, . For a fixed volume, how does pressure relate to the number of moles and temperature? Consider the ratio of final to initial conditions.
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Where marks are lost
- Reaching for "human error" or "only one trial." A source of error has to be a specific step in the method, not a general apology for the result.
- Joining the dots instead of drawing a curve.
- Naming a chemical instead of the property that distinguishes it, or vice versa. Answering with the nearest fact that comes to mind rather than the fact the command term and stem jointly ask for is a recurring way to answer a question that was not, quite, the one asked.